Synthesis of aromatic monopyrrolo-tetrathiafulvalene derivatives with variable degree of π‐conjugation
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Date
2021
Authors
Mncwangi, Sibusiso Nicko
Journal Title
Journal ISSN
Volume Title
Publisher
University of the Free State
Abstract
Tetrathiafulvalene (TTF, 1) and its derivatives have attracted much interest and found
widespread applications in molecular, supramolecular and materials chemistry.⁽¹⁾
Monopyrrolo‐tetrathiafulvalenes (MPTTF, 59) possess more extended π–system in
comparison to the parent TTF 1, better π–stacking capability and, therefore, they are capable
of forming stronger charge‐transfer complexes with molecular acceptors.⁽²⁾
Description
Dissertation (M.Sc.(Chemistry))--University of the Free State, 2021