Redox data of tris(polypyridine)manganese(II) complexes
| dc.contributor.author | Mtshali, Zinhle | |
| dc.contributor.author | Von Eschwege, Karel G. | |
| dc.contributor.author | Conradie, Jeanet | |
| dc.date.accessioned | 2022-09-14T10:25:22Z | |
| dc.date.available | 2022-09-14T10:25:22Z | |
| dc.date.issued | 2022 | |
| dc.description.abstract | Very little cyclic voltammetry data for tris(polypyridine)manganese(II) complexes, [MnII(N^N)3]2+, where N^N is bipyridine (bpy), phenanthroline (phen) or substituted bpy or phen ligands, respectively; are available in the literature. Cyclic voltammograms were found for tris(4,7-diphenyl-1,10-phenanthroline)manganese(II) perchlorate only. In addition to our recently published related research article, the data presented here provides cyclic voltammograms and corresponding voltage-current data obtained during electrochemical oxidation and the reduction of four [MnII(N^N)3]2+ complexes, using different scan rates and analyte concentrations. The results show increased concentration and scan rates resulting in higher Mn(II/III) peak oxidation potentials and increased peak current-voltage separations of the irreversible Mn(II/III) redox event. The average peak oxidation and peak reduction potentials of the Mn(II/III) redox events stayed constant within 0.01 V. Similarly, the average of the peak oxidation and reduction potentials of the ligand-based reduction events of [MnII(N^N)3]2+ were constant within 0.01 V. | en_ZA |
| dc.description.version | Publisher's version | en_ZA |
| dc.identifier | https://doi.org/10.3390/data7090130 | |
| dc.identifier.citation | Mtshali, Z., Von Eschwege, K.G., & Conradie, J. (2022). Redox data of tris(polypyridine)manganese(II) complexes. Data, 7, 130. https://doi.org/10.3390/data7090130 | en_ZA |
| dc.identifier.issn | 2306-5729 | |
| dc.identifier.uri | http://hdl.handle.net/11660/11901 | |
| dc.language.iso | en | en_ZA |
| dc.publisher | MDPI | en_ZA |
| dc.rights.holder | Author(s) | en_ZA |
| dc.rights.license | https://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | Tris(polypyridine)manganese(II) | en_ZA |
| dc.subject | Mn(II/III) oxidation | en_ZA |
| dc.subject | Cyclic voltammetry | en_ZA |
| dc.title | Redox data of tris(polypyridine)manganese(II) complexes | en_ZA |
| dc.type | Article | en_ZA |