Doctoral Degrees (Chemistry)

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Browsing Doctoral Degrees (Chemistry) by Author "Conradie, J."

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    Computational and characterization studies of homogeneous and heterogeneous tris(beta-diketonato) complexes with catalytic applications
    (University of the Free State, 2017-06) Gostynski, Roxanne; Conradie, J.; Erasmus, E.
    English: Nine [Mn(β-diketonato)3] [β-diketonato = dipivaloymethanato (dpm), 1; acetylacetonato (acac), 2; benzoylacetonato (ba), 3; dibenzoylmethanato (dbm), 4; trifluoroacetylacetonato (tfaa), 5; thenoyltrifluoroacetonato (tfth), 6; trifluorofuroylacetonato (tffu), 7; trifluorobenzoylacetonato (tfba), 8 and hexaflouroacetylacetonato, 9] complexes were synthesized by adapted methods from literature. An attempt was made to graft [Mn(β-diketonato)3] complexes 2-9 onto two dimensional (2-D) Si-wafer supports (S5-S12) via a silane linker. The X-ray photoelectron spectroscopy (XPS) Mn:F atomic ratio results of fluorine containing [Mn(β-diketonato)3] complexes grafted onto amino-functionalized Si-wafer (S9-S12) gave an indicaton that the [Mn(β-diketonato)3] complexes decomposed during the grafting process. Studying Mn2O3 on the hydroxylated Si-wafer surface by the use of XPS, it was confirmed that the Mn 2p photoelectron lines observed for S5-S12 consist mostly of Mn2O3 that has no interaction with the silane linker. Eight [Mn(β-diketonato)3] complexes 1-8 was wet impregnated onto various three dimensional (3-D) solid supports (S12- S28) to form [Mn(β-diketonato)3] model catalysts. Additionally a selection of [M(acac)3] complexes ([Co(acac)3], 12; [Rh(acac)3], 13, and [Ir(acac)3], 14) were grafted onto two dimensional (2-D) Si-wafer supports (S29-S31). While [M(acac)3] complexes ([Cr(acac)3], 10; [Fe(acac)3], 11; [Co(acac)3], 12; [Rh(acac)3], 13, and [Ir(acac)3], 14) were wet impregnated onto various three dimensional (3-D) solid supports (forming S32-S36). The model 2-D and 3-D catalysts were studied and characterized by the means of XPS, TGA and computational chemistry calculations. Selected model 2-D (S5, S7, S8, S12 and S29-S31) and Mn(acac)3 immobilized onto SiO2 (3-D catalysts, S14 as is and heat treated at 100, 130, 250 and 350 °C) were tested for the catalytic self-solvating reaction between ethanol and hexamethylenediisocyanate (HDI) to form hexamethylenediurethane (HDU) to mimic the industrial production of polyurethane. The model 2-D [Mn(β-diketonato)3] (S5, S7, S8 and S12) catalysts showed that as the total group electronegativity, 3(R + R'), increase a general decrease in turnover frequency (TOF) was observed. The model 2-D [M(acac)3] catalysts (S29-S31) showed that with an increase in the metal centre’s Pauling electronegativity a general increase in TOF was observed. The catalytic test on the Mn(acac)3 immobilized onto SiO2 showed that the sample heat treated at 100°C before hand has the highest TOF, which is most probably due to the loss of only one -diketonato ligand making it more active. The chromium(0) Fischer carbene complexes (Cr-FCCs) ([Cr(CO)4(PPh3)=C(OEt)(Fu)], C1; [Cr(CO)5=C(NHCy)(Fu)], C2; [Cr(CO)5=C(NHCy)(Th)], C3 and [Cr(CO)5=C(OEt)(ThTh)], C4) study was in collaboration with the research group of Dr. M Landman at the University of Pretoria. The four Cr(0) FCCs, were obtained and characterized by electrochemistry, XPS and computational chemistry calculations in this study. Penta-carbonyl Cr-FCCs [Cr(CO)5=C(OEt)(Fu)], C5, and [Cr(CO)5=C(OEt)(Th)], C6, were also supplied and anchored onto an amino-functionalized Si-wafer to create an immobilized Cr-FCCs C7 and C8. XPS results showed that the Cr(CO)5=C(OEt)(Fu)], C5, and [Cr(CO)5=C(OEt)(Th)], C6, was successfully anchored onto an amino-functionalized Si-wafer (C7 and C8). The electrochemical study of C1-4 showed that the oxidation potential (Epa) is influenced by the varied substituents on different sites of the Cr-FCCs. The oxidation order of the Cr-FCCs is: [Cr(CO)5=C(OEt)(ThTh)], C4 > [Cr(CO)5=C(NHCy)(Th)], C3 > [Cr(CO)5=C(NHCy)(Fu)], C2 > [Cr(CO)4(PPh3)=C(OEt)(Fu)], C1. The reduction followed the same trend except for the [Cr(CO)4(PPh3)=C(OEt)(Fu)], C1, complex that is reduced at a higher potential than the aminocarbene complexes, [Cr(CO)5=C(OEt)(ThTh)], C4 > [Cr(CO)4(PPh3)=C(OEt)(Fu)], C1 > [Cr(CO)5=C(NHCy)(Th)], C3 > [Cr(CO)5=C(NHCy)(Fu)], C2. The electronic energies of the different conformations obtained by the computational study showed that certain conformations are preferred over others. The computational results were in good agreement with experimental characterization method results. Computational study of HOMO and LUMO orbitals of the Cr- FCCs confirmed that the oxidation process is metal based and the reduction is based across the carbene ligand. The correlation of the oxidation potential (Epa) of the Cr0/Cr+1 redox couple and reduction potential (Epc) of the ligand based reduction with the HOMO energy (EHOMO) and LUMO energy (ELUMO) respectively, showed that with decreasing molecular orbital energy (HOMO and LUMO) an increase to more positive Epa and Epc potentials are obtained.
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    O,O'-chelated titanium(IV) complexes: a synthetic, kinetic, electrochemical and structural study
    (University of the Free State, 2008-11) Kuhn, Annemarie; Conradie, J.
    Synthetic routes to prepare fluorinated tetrahedral mono-β-diketonato titanium(IV) complexes, [Cp2Ti(β)+], octahedral bis-β-diketonato titanium(IV) complexes, Ti(β)2Cl2 and Ti(β)2biphen, as well as dimeric and tetrameric titanium(IV) complexes, were developed and optimised. All complexes were fully characterised, inter alia with UV/vis, IR, 1H and 19F NMR and X-ray crystallography. Further characterisation of the complexes was done by means of electrochemical and kinetic techniques. Solution phase studies using variable temperature 1H and 19F NMR show that all octahedral Ti(β)2Cl2 and Ti(β)2biphen complexes exist in solution as an equilibrium mixture of three cis isomers which rearrange via fast (on NMR timescale) intramolecular exchange processes. The CF3-containing Ti(β)2Cl2 complexes further participate in facile monomer dimer equilibrium, involving the interconversion of chemically distinct compounds. Substitution and exchange reactions involving the ligand(s) in the octrahedrally coordinated bis(β-diketonato)Ti(IV) complexes were investigated by means of UV/Vis and NMR kinetics. Experimental and computational data were mutually consistent indicating that the substitution processes proceeded via a seven-coordinate transition state according to an associative mechanism. The ligand exchange equilibria studies of Ti(β)2biphen complexes showed that the formation of mixed-ligand complexes is a random statistical process when the exchanging β-diketonato ligands contain the same number of CF3 groups, while the equilibrium favours the mixed ligand complex when they differ by one CF3 group, Electrochemical (cyclic voltammetric) studies on the Ti(IV) complexes and the β-diketones were performed in the weakly coordinating CH3CN or DCE/[NBu4][PF6] medium. The reduction of the Ti(IV) complexes Cp2Ti(biphen), Ti(β)2biphen and Ti(β)2Cl2 which form negatively charged reduced species, are to varying degrees chemically unstable. However, the [Cp2Ti(β)]+ complexes, forming a neutral reduced species, are chemically stable. The redox process is electrochemically reversible for Cp2Ti(biphen), Ti(β)2biphen and [Cp2Ti(β)]+ and irreversible for Ti(β)2Cl2 The reduction of the uncoordinated β-diketone, forming an unstable radical anion, is not coupled with a reverse oxidation process. However, when the β-diketone contains two aromatic side groups, the radical anion is stabilised long enough that the redox process, becomes electrochemically reversible (ΔEp < 90 mV) with an increasing peak aniodic current at higher scan rates. The electron density on the titanium(IV) metal centre was manipulated by changing the R groups on the coordinated β-diketonato ligand (RCOCHCOR¢) from electron donating (R = CH3, Ph) to strongly electron withdrawing (R = CF3). The formal reduction potential, E0', of the Ti(IV) complexes (or the reduction potential, Epc, of the ligands), correlated to parameters related to electron density on the Ti centre, i.e., χR + χR' (sum of the group electronegativities of R and R' groups on the β-diketonato ligand R'COCHCOR-) and pKa of the β-diketones. Calculated (DFT) ionisation potentials of [Cp2Ti(β)]+ complexes showed a linear correlation to χR + χR', allowing one to predict electronegativities of the R and R¢ groups if the calculated ionization potential is known.
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    Rhodium and iron complexes and transition states: a computational, spectroscopic and electrochemical study
    (University of the Free State, 2010-03) Conradie, Marrigje Marianne; Conradie, J.
    Abstract not available