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Synthesis, electrochemistry and density functional theory calculations on chrome and cobalt carbene and betadiketonato complexes
(University of the Free State, 2014)
English: Two series of metal(β-diketonato)3 complexes were synthesized: tris(β-diketonato)chromium(III) complexes (where β-diketonato = [R1COCHCOR2]- = acac, ba, dbm, tfba, tfth, tffu, tfaa, hfaa) and tris(β-diketonato)cobalt(III) ...
Syntheses, electrochemistry and spectroscopic studies of metallocene-containing porphyrin complexes with biomedical applications
(University of the Free State, 2010-05)
In this study, a series of carboxylic acid functionalised pyrrole derivatives and ferrocene- and ruthenocene-containing dipyrromethanes were synthesised. Porphyrin complexes bearing a mono-carboxylic acid functional group ...