Now showing items 1-6 of 6
Synthetic, electrochemical and structural aspects of ß-diketonato and carboxylate complexes of aluminium
(University of the Free State, 2008)
English: A series of ferrocene-containing tris-β-diketonato aluminium(III) complexes of the form Al(FcCOCHCOR)3 (R = CF3, CH3, C6H5, Fc with Fc = ferrocenyl) were synthesized and subjected to structural and electrochemical ...
Synthesis and functionalisation of polyepichlorohydrin
(University of the Free State, 2004-12)
During this study, benzo-15-crown-5 was synthesised as sodium cation scavenging ligand. This crown ether moiety was then functionalised to 4’-formylbenzo-15-crown-5 and 4’-(hydroxymethyl)benzo-15-crown-5. The first synthesis ...
Syntheses, electrochemistry and spectroscopic studies of metallocene-containing porphyrin complexes with biomedical applications
(University of the Free State, 2010-05)
In this study, a series of carboxylic acid functionalised pyrrole derivatives and ferrocene- and ruthenocene-containing dipyrromethanes were synthesised. Porphyrin complexes bearing a mono-carboxylic acid functional group ...
Synthesis, electrochemical, kinetic and thermodynamic properties of new ferrocene-containing betadiketonato rhodium(I) complexes with biomedical applications
(University of the Free State, 2002-11)
English: Synthetic routes to prepare new ferrocene-containing β-diketones, FcCOCH2COR, with Fc = ferrocenyl, R = H, CH3, CH2CH3, CH(CH3)2 and C(CH3)3, have been developed. Rhodium complexes of the type [Rh(FcCOCHCOR)(cod)] ...
Synthesis and characterization of 3,3”-dihydroxy-[1,1’:4’,1”-terphenyl]-4,4”- dicarboxylic acid derivatives as precursors for functionalized Co-MOF-74-III materials
(University of the Free State, 2017-01)
English: A series of new 4,4”-di[methoxyethoxymethoxy]-[1,1’:4’,1”-terphenyl]-3,3”-di[methoxyethoxymethoxycarbonyl] derivatives were synthesised as possible linkers for MOF-74-III derivatives. The following products were ...
Synthesis and electrochemistry of novel new ferrocene-containing water-soluble macromolecules with biomedical applications
(University of the Free State, 2002-01)
English: The side effects associated with chemotherapy have caused an intensive research effort to find new ways of delivering a chemotherapeutic drug to a cancerous growth. One of these includes use of polymeric drug ...