Gomo, ModreckMoleme, Malefa Florence2024-02-142024-02-142023http://hdl.handle.net/11660/12428Thesis (Ph.D.(Geohydrology))--University of the Free State, 2023The fluid electrical conductivity (FEC) profiling method has been commonly applied to aid in the compilation of site-specific conceptual models and understanding of the subsurface environment. Although research has recently been conducted to help improve the knowledge and understanding of the evolution of FEC profiles under natural and saline contaminated environments within the fractured-rock aquifer system, a research gap still exists for such studies in other aquifer types. The type of aquifer system plays a significant role in determining the migration patterns and behaviour of contaminants. Therefore, it is expected that the evolution of FEC profiles in different aquifer systems will vary, and this needs to be understood. It is against this background that this research aimed to investigate the behaviour of FEC profiles associated with a saline contaminant plume in typical unconfined porous and weathered basement aquifer systems, using laboratory-based aquifer models. This was done to improve the conceptual understanding of contaminant migration within these aquifer systems, which will essentially improve the interpretation of their FEC profiles. To achieve this, two physical models were developed in the laboratory to represent an unconfined porous aquifer system and a weathered basement aquifer system. The performance of the models was evaluated and tested, and subsequently used to investigate the progression of FEC profiles associated with a saline contaminant plume. The outcome of the laboratory tests was also verified in the field. This study also explored the effects that the distance of a source from a monitoring point would have on the shape of FEC profiles. Unlike previous studies which conducted the FEC profiling technique under induced groundwater flow, this study investigated the efficiency of a non-invasive approach of applying the method under natural gradient conditions. From the analysis of profiles obtained within the two simulated aquifer systems conceptual profiles were developed. Within the unconfined porous aquifer system, FEC profiles recorded from the borehole located closer to the source were notably different from the FEC profiles recorded from a borehole positioned further away from the source, thus it was evident that the distance of a monitoring point from the source influenced the orientation of the plume, and ultimately the resulting FEC profile. This brought to light the phenomenon of “plume orientation”. The orientation of the plume is usually disregarded in groundwater models and assessments, however this research showed that it is an important aspect which can be used to assist with FEC data interpretation and contaminated site characterisation studies. The orientation of the plume was strongly influenced by the magnitude of the forces acting upon it, primarily the gravitational and advection force. Closer to the source, the plume took on a vertical to sub-vertical orientation, whereas as the plume continued to migrate further away from the source it aligned with the flow lines of the system which resulted in a horizontal orientation. From the analysis of the weathered basement aquifer system two distinct signatures were identified and conceptualised: the low FEC profile and the elevated FEC profile. The low FEC profile not only represented a profile captured under natural conditions in the absence of contamination, but also represented a profile that would be observed when the majority of the contaminant has passed the borehole and the system was in the process of re-establishing initial conditions. It had three distinct zones: the weathered zone, transition zone, and the impermeable zone. The elevated FEC conceptual profile was associated with contaminated groundwater conditions within the weathered basement aquifer system. It had two distinct zones: the weathered zone and the impermeable zone.enAquiferborehole profilingconceptual profilecontaminant plumefluid electrical conductivitygroundwater flowmass transportnatural waternon-invasive approachporous mediatracer breakthrough curveunconfined porous aquifer systemweathered basement aquifer systemThesisUniversity of the Free State