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Photochemistry of (+)-catechin and (-)-epicatechin
(University of the Free State, 2008-01)
Despite the well known fact that photolysis of free phenolic catechins give rise to isomerisation at the C-2 position (e.g. (-)-cis epicatechin converts to the sterically less hindered (-)-trans isomer), researchers have ...
Development of methodology for the synthesis of 4-arylflavan-3-ol lactones
(University of the Free State, 2008-05)
English: The phenolic content of the heartwood of Peltophorum africanum (African wattle) and Burkea africanum (Red syringa) proved to contain a variety of compounds including the novel 4-arylflavan-3-ol lactones, ...
Studies directed at the stereoselective synthesis of flavonoids through the hydrogenation of prochiral precursors
(University of the Free State, 2008-11)
English: The in vitro studies of biologically active flavonoids are hampered by the inaccessibility of all monomeric units in enantiomerically pure form. Although a number of these scalemic flavonoids can be obtained ...
Structure and synthesis of a novel homoisoflavanone from Scilla natalensis and synthesis of selected procyanidins through the C-4 functionalization of flavan-3-ols
(University of the Free State, 2008-05)
English: Scilla natalensis planch (Hyacinthaceae), commonly known as Wild squill, Blue squill, Blue hyacinth, Blouberglelie, Blouslangkop, Inguduza, is one of the plants that are widely used in traditional medicines and ...