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A structural, electrochemical and thermal study of new mono- and bimetallic long chain carboxylates
(University of the Free State, 2015-07)
English: Two methods were used for the synthesis of the mixed-metal carboxylatido complexes. The first method involves the reaction of one equivalent of [Pd3 II(μ-OOC(CH2)nCH3)6] where n = 4, 6, 8, or 10 with three ...
Synthetic, electrochemical and kinetic studies of phosphinites and their rhodium(I) complexes
(University of the Free State, 2015-06-24)
English: Organophosphorus ligands of the type, C6H5XPPh2, where X = O, S and NH, meta- and para-Ph2POC6H4OPPh2, were synthesised by the reaction between chlorophenylphosphine and the desired phenyl substituent in the ...
Synthesis, characterization and electrochemical studies of osmocenyl alcohols with biomedical applications
(University of the Free State, 2015-01)
English: A series of osmocene-containing carboxylic acids, Oc(CH2)mCOOH where m = 1, 2 and 3, and osmocene-containing alcohols, Oc(CH2)nOH where n = 1, 2, 3 and 4, were obtained in multiple synthetic steps and characterised ...