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dc.contributor.authorMtshali, Zinhle
dc.contributor.authorVon Eschwege, Karel G.
dc.contributor.authorConradie, Jeanet
dc.date.accessioned2022-09-14T10:25:22Z
dc.date.available2022-09-14T10:25:22Z
dc.date.issued2022
dc.identifierhttps://doi.org/10.3390/data7090130
dc.identifier.citationMtshali, Z., Von Eschwege, K.G., & Conradie, J. (2022). Redox data of tris(polypyridine)manganese(II) complexes. Data, 7, 130. https://doi.org/10.3390/data7090130en_ZA
dc.identifier.issn2306-5729
dc.identifier.urihttp://hdl.handle.net/11660/11901
dc.description.abstractVery little cyclic voltammetry data for tris(polypyridine)manganese(II) complexes, [MnII(N^N)3]2+, where N^N is bipyridine (bpy), phenanthroline (phen) or substituted bpy or phen ligands, respectively; are available in the literature. Cyclic voltammograms were found for tris(4,7-diphenyl-1,10-phenanthroline)manganese(II) perchlorate only. In addition to our recently published related research article, the data presented here provides cyclic voltammograms and corresponding voltage-current data obtained during electrochemical oxidation and the reduction of four [MnII(N^N)3]2+ complexes, using different scan rates and analyte concentrations. The results show increased concentration and scan rates resulting in higher Mn(II/III) peak oxidation potentials and increased peak current-voltage separations of the irreversible Mn(II/III) redox event. The average peak oxidation and peak reduction potentials of the Mn(II/III) redox events stayed constant within 0.01 V. Similarly, the average of the peak oxidation and reduction potentials of the ligand-based reduction events of [MnII(N^N)3]2+ were constant within 0.01 V.en_ZA
dc.language.isoenen_ZA
dc.publisherMDPIen_ZA
dc.subjectTris(polypyridine)manganese(II)en_ZA
dc.subjectMn(II/III) oxidationen_ZA
dc.subjectCyclic voltammetryen_ZA
dc.titleRedox data of tris(polypyridine)manganese(II) complexesen_ZA
dc.typeArticleen_ZA
dc.description.versionPublisher's versionen_ZA
dc.rights.holderAuthor(s)en_ZA
dc.rights.licensehttps://creativecommons.org/licenses/by/4.0/


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