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dc.contributor.advisorRoelofse, Frederick
dc.contributor.advisorGauert, Christoph D. K.
dc.contributor.advisorGiebel, R. Johannes
dc.contributor.advisorRentel, Raimund
dc.contributor.authorDu Plessis, Pieter George
dc.date.accessioned2019-12-05T06:14:07Z
dc.date.available2019-12-05T06:14:07Z
dc.date.issued2019-03
dc.identifier.urihttp://hdl.handle.net/11660/10359
dc.description.abstractThe Palabora Complex, also known as the Palabora Carbonatite Complex, is situated in the Limpopo Province, next to the town of Phalaborwa. The complex intruded the Kaapvaal Craton in early Proterozoic times. The centre of the complex is known as the Loolekop pipe and hosts the youngest rock types of the complex. These rock types are phoscorite (older), banded carbonatite (younger), and transgressive carbonatite (youngest). Transgressive carbonatite hosts one of the world’s largest copper deposits in the form of sulphide group minerals. The paragenesis of the various sulphide minerals is not well known, and a back and forth dispute exists of the formational processes (e.g. magmatic, hydrothermal, autometasomatic, etc.) which led to sulphide mineral crystallisation. This study shows that these sulphide minerals form part of different repetitive assemblages. These assemblages have distinguishable mineralogical, petrographical, geochemical, and paragenetic characteristics. Some assemblages that contain more than one generation of a certain sulphide mineral show differences in mineral chemistry (e.g. pentlandite group minerals, pyrrhotite, chalcopyrite, and sphalerite). The same assemblages that form part of transgressive carbonatite are also found in banded carbonatite. However, the sulphide mineral assemblage of phoscorite is completely different. This is indicative of different sulphide mineralisation events within the Loolekop pipe. The majority of transgressive carbonatite minerals show evidence of a magmatic origin, and most of them have been modified due to hydrothermal activity. Both processes are also responsible for sulphide mineral formation. This study also shows the discovery of sulphide minerals (e.g. heazlewoodite and shandite) and Cu-rich veinlets that have not been observed from this area in the past.en_ZA
dc.description.sponsorshipNational Research Foundation (NRF)en_ZA
dc.language.isoenen_ZA
dc.publisherUniversity of the Free Stateen_ZA
dc.subjectDissertation (M.Sc. (Geology))--University of the Free State, 2019en_ZA
dc.subjectParagenesisen_ZA
dc.subjectSulphide mineralsen_ZA
dc.subjectPalabora carbonatite complexen_ZA
dc.subjectLoolekop pipeen_ZA
dc.subjectPhoscoriteen_ZA
dc.subjectTransgressive carbonatiteen_ZA
dc.subjectBanded carbonatiteen_ZA
dc.subjectMagmaticen_ZA
dc.subjectHydrothermalen_ZA
dc.subjectSulphide mineral assemblagesen_ZA
dc.titleThe parageneses of sulphide minerals in transgressive carbonatite of the Palabora Carbonatite Complex, South Africaen_ZA
dc.typeDissertationen_ZA
dc.rights.holderUniversity of the Free Stateen_ZA


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